Product ID:FORANE 141B
MSDS Date:05/09/1994
FSC:6850
NIIN:00N064928
MSDS Number: BZMDK

VAN WATERS & ROGERS INC

6100 CARILLON POINT
KIRKLAND, WA 98033
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 206-889-3400

Cage: DO735

VOPAK USA INC

KIRKLAND, WA 98033-7357 US

Telephone: 425-889-3400/425-889-3617

Cage: 0STM5

ETHANE, 1,1-DICHLORO-1-FLUORO-;

CAS: 1717-00-6

RTECS: KI0997000

OSHA PEL N/K

ACGIH TLV: N/K

SUCH AS ALUMINUM, MAGNESIUM/ZINC & STRONG

RTECS: 9999999ZZ

DIOXIDE AND CHLORINE.

RTECS: 9999999ZZ

IN RAPID HEARTBEAT (TACHYCARDIA), IRREGULAR

RTECS: 9999999ZZ

OF FEMALE RATS TO 20,000PPM DURING PREGNANCY CAUSED

RTECS: 9999999ZZ

PUP WT. NO EVID OF BIRTH DEFECTS. SIMILAR MATERNAL

RTECS: 9999999ZZ

FETAL DEVELOPMENT. IN VITRO CHROMOSOME ABERRATION

RTECS: 9999999ZZ

MICRONUCLEUS ASSAY WAS NEG AT EXPOS LEVELS UP TO

RTECS: 9999999ZZ

FOR 1 YR CAUSED MINOR REDUCTIONS IN BODY WT GAIN &

RTECS: 9999999ZZ

BENIGN TESTICULAR TUMORS HAVE BEEN SEEN IN RATS

RTECS: 9999999ZZ

FINDINGS TO HUMAN RISK ASSESSMENT IS EQUIVOCAL.

RTECS: 9999999ZZ

COLLECT REMAINDER OF SPILL W/ABSORB MATL &

RTECS: 9999999ZZ

CLTHG BEFORE REUSE.

RTECS: 9999999ZZ

DESIGNED FOR FLAMMABLE GAS ATMOSPHERES TO REMOVE

RTECS: 9999999ZZ

LINED GLOVES ARE RECOMMENDED FOR PROTECTION

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50: (ORAL, RAT) > 5 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHLOROFLUOROCARBON (CFC) MATLS HAVE
PRDCED SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD
HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (IE, EPINEPHRINE) MAY BE
CONTRA-INDICATED EXCEPT FOR LI FE-SUSTAINING USES IN HUMANS
ACUTELY/CHRONICALLY EXPOS TO CFCS . EYE: VAP & LIQ ARE IRRIT. SKIN:
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CNTCT W/LIQ MAY CAUSE DRYING. CHEM IS
NOT IRRIT/SENSITIZER. TARGET ORGAN: CNS, RESP SYS, HEART. TOX
COMMENTS:DENSE VAP DISPLACES BRTHG AIR IN CONFINED/NONVENT AREAS.
INHAL CONC VAPS CAN CAUS E DROW, UNCON, HDCH, RESP DEPRESS & DEATH
DUE TO ASPHY. ALSO INCRS SENSITIVITY OF HEART TO ADRENALIN, POSS
RSLTG (ING 4)
Medical Cond Aggravated by Exposure:PERSONS WITH PREEXISTING HEART
DISEASE MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:INGEST: DO NOT INDUCE VOMIT. GIVE WATER TO DRINK. GET MED
ATTN. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. SKIN:
FLUSH AREA W/PLENTY OF WATER. REMOVE CONTAMD CLTHG. WASH CLTHG
BEFORE REUSE. G ET MED ATTN. EYES: IMMED FLUSH W/PLENTYOF CLEAN
WATER FOR AT LEAST 15 MIN. GET MED ATTN. INHAL: REMOVE TO FRESH
AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN.
GET MED ATTN.

Flash Point Method:TCC
Flash Point:NONE
Lower Limits:7.4%
Upper Limits:15.5%
Extinguishing Media:USE WATER SPRAY OR FOG, CARBON DIOXIDE, DRY
CHEMICAL OR WATER STREAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT . KEEP CONTAINERS COOL.
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCL FLUORIDES,
CHLORIDES & PHOSGENE . MAY DECOMPOSE DURING CNTCT W/FLAMES, HEATING
ELEMENTS OR IN COMBUST ENGINES (SUPDAT)

Spill Release Procedures:REMOVE/EXTING IGNIT/COMBUST SOURCES. EVACUATE
ENCLSD SPACES UNTIL GAS IS DISPERSED. KEEP UPWIND. STOP LEAK IF
POSS W/OUT RISK. DISPERSE GAS W/FLOOR LEVEL FORCED-AIR VENT. EXHST
VAPS OUTDOORS. CNTN SPI LL BY BLDG DIKE USING ABSORB MATL. (ING12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT GET IN EYES, ON SKIN/CLTHG. DO
NOT BREATHE VAP, MIST/GAS. KEEP CNTNR CLSD. KEEP AWAY FROM HEAT,
SPK & FLAMES. STORE IN TIGHTLY CLSD CNTNRS.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF
ARC WELDING/OPEN FLAMES/HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE
FORM OF CHLORIDES/FLUORIDES/PHOSGENE . EMPTY CNTNR MAY CNTN HAZ
RESIDUE. DO NOT DROP/REUSE/REFILL CNTNR. (ING 14)

Respiratory Protection:IN INADEQUATELY VENTILATED AREAS, NIOSH/MSHA
APPROVED (TC-9C) SUPPLIED AIR RESPIRATOR OR SELF-CONTAINED
BREATHING APPARATUS IS REQUIRED.
Ventilation:USE W/ADEQ VENT. CHECK AIR FOR CONTAMINANT & FOR OXYGEN
DEFICIENCY. WHERE VENT IS INADEQ, USE LOC EXHST SYS (ING 17)
Protective Gloves:SYNTHETIC RUB SUCH AS NEOPRENE. (ING 18)
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:PROTECT ALL EXPOSED SKIN AND LIQUID CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: RELEASING IRRIT, TOX & CORR GASES. CNTNR MAY EXPLODE IF
HEATED DUE TO RSLTG PRESS RISE. SOME MIXS OF HCFCS &/OR HFCS &
AIR/OXYGEN MAY BE COMBUST IF PRESSURIZED & EXPOS TO EXTREME
HEAT/FLAME . CNDTNS TO AVOID: LIGHTS, STATIC ELECTRICITY,
COMBUSTION ENGINES, IGNITION SOURCES, ETC.

Boiling Pt:B.P. Text:89.6F,32.0C
Melt/Freeze Pt:M.P/F.P Text:-154F,-103C
Vapor Pres:10 PSIA
Vapor Density:4.0
Spec Gravity:1.25 (H*2O=1)
Solubility in Water:SLIGHT
Appearance and Odor:CLEAR, COLORLESS, LIQUID AND GAS WITH FAINT
ETHEREAL (ETHER-LIKE) ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG ALKALIS, STRONG OXIDIZERS. AVOID CNTCT W/STRONG ALKALI/ALKALINE
EARTH METALS, FINELY POWDERED METALS (ING 2)
Stability Condition to Avoid:THERMAL DECOMP DUE TO EXPOS TO HEAT
(>800F) OR FIRE. FLAMES, SPKS, EXTREMELY HOT METAL, HEATING
ELEMENTS, PILOT (SUPDAT)
Hazardous Decomposition Products:PHOSGENE . THERMAL DECOMP PRODS INCL
HYDROGEN FLUORIDE, HYDROGEN CHLORIDE, CARBON MONOXIDE, CARBON (ING
3)

Waste Disposal Methods:RECYCLE OR RECLAIM IF POSSIBLE. RECLAIMED
MATERIAL MAY BE INCINERATED BUT TOXIC & CORROSIVE COMBUSTIBLE
PRODUCTS (HP & HCL) MUST BE HANDLED APPROPRIATELY. CONSULT FEDERAL,
STATE AND LOCAL AUTHORITIES FOR PROPER DISPOSAL PROCEDURES.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.